Food and agriculture

Ethylene is the ripening hormone. Climacteric fruits produce it themselves and respond to it — a relationship that has governed storage practice for decades. The practical question is not whether ethylene can be measured, but from which concentration you need to see it. And the answer spans more than four orders of magnitude depending on the task.

The concentration ranges that matter

We put the numbers first because they decide suitability. For ethylene, NZGS 2 has a limit of detection warranted in the datasheet of 400 ppb, that is 0.4 ppm.

SituationEthylene concentrationNZGS 2, 400 ppb warranted
Ripening room, deliberate gassing100–150 ppm far above — clearly detectable
Storage of climacteric fruit, measured0.014–4.9 ppm upper part of the range detectable
Triggering irreversible ripening0.1–1.0 ppm partly, from 0.4 ppm
General threshold for ethylene action on plantsfrom about 0.1 ppm below the limit of detection
Recommendation for sensitive producebelow 0.005 ppm roughly 80× below — not detectable

400 ppb equals 0.4 ppm. The warranted value comes from datasheet rev. 3.3.0, determined at 25 °C and 45 % relative humidity. The storage concentrations are horticultural working figures from the literature and vary with cultivar, temperature and storage duration.

What this means For controlling ripening rooms and for monitoring storage in the upper ppm range the sensor is suitable. For demonstrating that a store keeps below the 0.005 ppm recommendation it is not — that value lies roughly eighty times below the warranted limit of detection. Anyone with that task needs a different method, as a rule gas chromatography or photoacoustics.

That boundary sits deliberately near the top of this page. A sensor installed in the wrong application creates confidence in a measurement that is not happening — and with stored produce that costs more than no measurement at all.

The ripening room: the case that fits

For deliberate ripening, ethylene is used at concentrations around 100 to 150 ppm; for tomatoes roughly 100 ppm over about 48 hours. That is two and a half orders of magnitude above the limit of detection.

What matters here is not sensitivity but reliability over time. A ripening room is warm, humid and full of volatile compounds from the produce itself. The sensor has to stay stable under those conditions and must not respond to every other gas that happens to be forming.

Why selectivity counts here in particular

A store full of fruit is anything but quiet in gas-chemical terms. Ripening and over-stored produce releases:

  • Ethanol from anaerobic fermentation — the classic marker for incipient spoilage, especially in stores with reduced oxygen.
  • Acetaldehyde and esters, which make up the fruit aroma and increase with ripeness.
  • Terpenes and further compounds depending on cultivar.

A sensor that outputs only a sum reading sees a rising curve and cannot say whether the produce is ripening or spoiling. Yet that is exactly the distinction that matters: ripening is wanted and controllable, spoilage is a loss.

NZGS 2 carries four sensing elements on a die of 1.15 × 1.15 mm. Because each element has a different layer and a different operating temperature, one gas event produces four different signal traces, and the substance is determined from the ratio between them. How that works in detail is on the technology page.

Ethanol as a spoilage marker

For ethanol the datasheet warrants a limit of detection of 30 ppb. That is more than an order of magnitude more sensitive than for ethylene, and it lies in a range where incipient fermentation becomes detectable before it is visible or noticeable by smell.

In practice this is the more interesting channel. Ethylene says produce is ripening — which it does anyway, and usually as planned. Ethanol says something is going wrong: too little oxygen, too warm, a damaged batch. Together the two give a picture that neither value provides alone.

Cold chain and transport

The same arithmetic applies in containers and trailers, under harder conditions: tight installation space, vibration, changing temperature and humidity, no maintenance access in transit. Form factor and power consumption co-decide here — a component in QFN-8 at 2.8 × 2.8 × 1.6 mm drawing around 70 mW can be accommodated; a laboratory instrument cannot.

Humidity deserves attention. The permitted operating range extends to 90 % relative humidity, non-condensing. In a refrigerated container that is a real boundary condition, not a formality: temperature and humidity belong in the measurement, because both shift the signal and compensation otherwise has no data basis.

Ammonia in refrigeration

Large cold stores frequently use ammonia as a refrigerant. Ammonia is detected by NZGS 2, but the datasheet warrants no limit of detection for it. Measured values and test conditions can be determined on a project basis.

Not a safety function Leak detection on ammonia plant is governed by its own rules and approved gas warning systems. NZGS 2 delivers a measurement, not a safety function, and does not replace a compliant gas detection installation.

What the sensor does not do in this application

  • It does not reach the storage recommendation for sensitive produce. 0.005 ppm lies far below the warranted limit of detection. That is the most important restriction on this page.
  • It is not a calibrated analyser. A limit of detection states from when a substance is reliably detected, not the accuracy with which its concentration can be reported. Reporting concentrations requires calibration for the use case.
  • It has to be trained on the produce. Which substances separate depends on cultivar, ripeness, temperature and storage atmosphere. A classification for apples in controlled-atmosphere storage is not the same as for bananas in a ripening room.
  • It ages and it is vulnerable. Baseline drift is compensable. Silicone compounds, by contrast, poison the tin dioxide layer irreversibly — that belongs in the choice of housing, seals and adhesives.

How a project begins

At the outset stands the question of whether the target substances separate cleanly for your produce and your storage conditions. That cannot be derived from specifications, only measured. The evaluation kit with read-out electronics and software exists for this: it records the four signal traces, extracts the features and shows whether the target substances form separate regions in feature space.

What gets recorded is reference air for the baseline, the target substances at known concentrations, and the interferents that realistically occur in the store — plus the boundary conditions temperature and humidity across the expected range. All specifications of the component are in the datasheet extract.

Does the measuring range fit your task?

Tell us what you store and in which concentration range you need to measure. If 400 ppb is too coarse for your application we will say so — and tell you what to consider instead.

Send an enquiry

Storage and ripening concentrations after horticultural literature and postharvest practice; sensor characteristics after NANOZ NZGS 2, datasheet rev. 3.3.0.

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